Activation of sulfite by metal-organic framework-derived cobalt nanoparticles for organic pollutants removal

Sulfite (SO₃^2-) activation is one of the most potential sulfate-radical-based advanced oxidation processes, and the catalysts with high efficiency and low-cost are greatly desired. In this study, the cobalt nanoparticles embedded in nitrogen-doped graphite layers (Co@NC), were used to activate SO₃^2- for removal of Methyl Orange in aqueous solution. The Co@NC catalysts were synthesized via pyrolysis of Co²⁺-based metal-organic framework (Co-MOF), where CoO was firstly formed at 400℃ and then partially reduced to Co nanoparticles embedded in carbon layers at 800℃. The Co@NC catalysts were more active than other cobalt-based catalysts such as Co²⁺, Co₃O₄ and CoFe₂O₄, due to the synergistic effect of metallic Co and Co_xO_y. A series of chain reaction between Co species and dissolved oxygen was established, with the production and transformation of SO₃^•-, SO₅^2-, and subsequent active radicals SO₄^•- and HO•. In addition, HCO₃^- was found to play a key role in the reaction by complexing with Co species on the surface of the catalysts. The results provide a new promising strategy by using the Co@NC catalyst for SO₃^2- oxidation to promote organic pollutants degradation.