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Effect of surface roughness on the solar evaporation of liquid marbles
Yijun Feng1, Guansheng Yao1, Jinliang Xu1
1Beijing Key Laboratory of Multiphase Flow and Heat Transfer for Low Grade Energy Utilization, North China Electric Power University, Beijing 102206, PR China.
Hypothesis:
Nanostructured materials are widely used for solar energy harvesting and conversion due to their excellent photothermal properties. It is generally accepted that the better the light absorption ability, the better the photothermal conversion efficiency.
Experiment:
A series of experiments in solar evaporation of liquid marbles (LMs) by coating the droplets with Fe3O4, Ni nanoparticles (NPs) and carbon nanotubes (CNTs) are conducted.
Findings:
Conversely, we found that the surface roughness of solar absorber plays a significant role in solar evaporation rather than the light absorption. The results disclose that the Fe3O4 NPs with the lowest absorptivity has the largest roughness on drop surface, while that of CNTs show the opposite properties. The evaporation dynamics of LMs are featured with dome or constant spherical collapse with different roughness. Such dynamic difference arises from the mechanical competition between the capillary force and interparticle interaction. Besides, the strong light-harvesting and near-field radiation enabled by the rough surfaces enhance the solar evaporation. The Fe3O4-LM shows the highest evaporation rate of 6.55 μg/s, which is 1.09 and 1.30 times larger than that of Ni-LM and CNT-LM, respectively. Numerical analysis reveals that the rough surface with stacking arrangement of NPs greatly enhances the light-induced electromagnetic field and heat concentration over the interface, leading to a plasmon-coupling boundary with high temperature for the fast evaporation. Uncovering these properties could be of much help for developments of heatable miniature evaporators or reactors and their counterparts, permitting a broad range of processes with precise temperature and kinetic control.
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