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Published on: March 20, 2015
Rapid Immobilization of Silver Nanoparticles via Amino-quinone Coatings Enables Surface-Enhanced Raman Scattering
Tian Gao1, Di Zhou1, Zhi-Kang Xu1
1MOE Key Laboratory of Macromolecular Synthesis and Functionalization, MOE Engineering Research Center of Membrane and Water Treatment Technology, and Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China.
Abstract:
Immobilization of metal nanoparticles (NPs) on flexible substrates for surface-enhanced Raman scattering (SERS) has received great attention. Anchoring NPs on substrates generally involves the process of surface modification, thanks to its simple, universal, and nondestructive features. 2-Hydroxy-1,4-naphthoquinone (HNQ), a plant-derived compound used to dye hairs and nails, may interact with polyamine or metal ions to form a surface coating. Here, we report the formation of amino-quinone coatings via the co-deposition of HNQ and polyethyleneimine, which provides a functionalized platform to rapidly immobilize Ag NPs on substrates such as a poly(dimethylsiloxane) (PDMS) film to fabricate Ag-PDMS substrates for SERS detection. The detection concentrations are down to 10-8 M for rhodamine 6G. This work expands the system of surface co-deposition and further provides a facile route to prepare a highly efficient SERS substrate.
