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Energetic Salts of Sensitive N,N'-(3,5-Dinitropyrazine-2,6-diyl)dinitramide Stabilized through Three-Dimensional

Jatinder Singh1, Ajay Kumar Chinnam1, Richard J Staples2

  • 1Department of Chemistry, University of Idaho, Moscow, Idaho 83844-2343, United States.

Inorganic Chemistry
|October 4, 2022
PubMed

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Nitrous acid is a relatively weak and unstable acid prepared in situ by the reaction of sodium nitrite and cold, dilute hydrochloric acid. In an acidic solution, the nitrous acid undergoes protonation when it loses water to form a nitrosonium ion—an electrophile. Nitrous acid reacts with primary amines to give diazonium salts. The reaction is called diazotization of primary amines.
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