Flexible Mn₃O₄/MXene Films with 2D-2D Architectures as Stable and Ultrafast Anodes for Li-Ion Batteries

Mn₃O₄ is regarded as a promising anode material for lithium-ion batteries (LIBs) based on its ultrahigh theoretical capacity (937 mAh g^-1) and low cost but suffers from poor electronic conductivity and large volume variation during the lithiation/delithiation process, which result in dramatic capacity fading and inferior rate capability. Ti₃C₂T MXene, a novel two-dimensional transition metal carbide with metallic conductivity, excellent mechanical properties, and hydrophilic surface, could be an ideal candidate to improve the lithium storage performance of Mn₃O₄. Here, a unique flexible, 2D-2D Mn₃O₄/MXene film is fabricated by assembling 2D Mn₃O₄ with Ti₃C₂T nanosheets through a simple vacuum filtration approach. In this unique 2D-2D nanostructure, MXene nanosheets buffer the volume change of Mn₃O₄ during the charge/discharge process. Moreover, the introduction of MXene enables the fabricated 2D-2D nanostructure with excellent flexibility and can be directly used as an electrode for LIBs, which is beneficial for enhancing the energy density of the assembled batteries. As a result, the flexible film of Mn₃O₄-MXene-8-2 shows excellent lithium storage performances in terms of specific capacity (931 mAh g^-1 at 0.05 A g^-1), rate capability (624 mAh g^-1 at 1 A g^-1), and cycling stability, demonstrating its great potential for the application in LIBs.