Transfer of a Photocatalytically Active TiO₂ Nanotube Array onto Cementitious Materials

Due to a recent change concerning the risk and hazard regulations of titanium dioxide powders, which possibly leads to restrictions in the use of those materials in photocatalytic applications, an alternative utilization of titanium dioxide is shown in this work. This is achieved by covering surfaces of cement-based materials with a regular-shaped monolayer of photocatalytically active titanium dioxide nanotube arrays which are not affected by the regulation changes due to their shape and size. This study delivers a proposal for the synthesis of TiO₂ nanotubes via anodization and their post-treatment to generate detached crystalline nanotube arrays which can be easily transferred onto material surfaces. We show that the transfer of such nanostructured materials can be achieved by modifying the cement mold, showing the opportunity for applying the material to precast elements. The composite material is characterized by referencing the morphology and photocatalytic activity.