Engineered and green natural pozzolan-nano silica-based alkali-activated concrete: shrinkage characteristics and life...

Alkali-activated concrete (AAC) or binders (AABs) have emerged as a substitute to conventional ordinary Portland cement (OPC)-based concrete owing to their techno-ecological merits. Saudi Arabia has vast resources of natural pozzolan whose impact on some fresh and hardened properties was encouraging; however, the long-term shrinkage behavior of AABs and life cycle assessment (LCA) of the developed product is yet to be explored. Therefore, this study evaluates shrinkage characteristics and LCA of Saudi natural pozzolan (NP)-based AAC. The synergistic impact of admixing nano-silica (NS) up to 7.5% dosage was also observed on the properties of engineered AABs in comparison with OPC-based concrete. The shrinkage properties were correlated with the microstructure and pore structure. The study revealed that the shrinkage properties of both NP-based AABs and OPC-based concrete are comparable. However, adding NS increased the drying shrinkage strain because of the finer pore structure than AABs without NS, which was confirmed through nuclear magnetic resonance (NMR). The maximum average drying shrinkage strain of 510 με was recorded in the OPC concrete, whereas in the engineered AAC with 0, 1, 2.5, 5, and 7.5% NS, it was 486, 537, 568, 601, and 651 με, respectively. It is postulated that the NP can be beneficially valorized in the production of green AABs without compromising the shrinkage characteristics, while the NS is favorable for enhancing the strength and refinement of the pore matrix. Besides, the LCA indicated the feasibility of recycling the high volume of natural waste by AAB technology, which significantly lowers the carbon footprints and minimizes the environmental implications in infrastructural applications.