Multi-Functionalization Integration into the Electrospun Nanofibers Exhibiting Effective Iodine Capture from Water

Efficient capture of radioiodine from aqueous solutions is of importance for sustainable development of nuclear energy and protection of the environment. However, current adsorbents under exploration suffer from limited adsorption capacity and powder form that are unfavorable for practical applications. Herein, we applied a "multi-functionalization integration" idea to construct novel electrospun fiber adsorbents (N-MOF-PAN fibers) containing cationic quaternary ammonium groups, uncharged amine groups, and porous MOF material (UiO-66-NH₂), which in synergy adsorb iodine effectively from both saturated I₂ aqueous solution and I₃^- aqueous solution. Iodine species (94.6%) could be removed from saturated I₂ solution within 180 min, and 98.7% of iodine species were captured from I₃^- solution within 240 min. Additionally, the N-MOF-PAN fibers exhibited high iodine uptake capacities of 3.56 g g^-1 from a concentrated KI/I₂ aqueous solution and 3.61 g g^-1 from the Langmuir isotherm model, surpassing many reported iodine adsorbents in the aqueous medium. Characterization and mechanism analysis indicated that multiple active sites simultaneously attribute to the high binding affinity toward iodine species through physical adsorption and chemical adsorption. Furthermore, benefiting from their macroscopic architecture, N-MOF-PAN fibers were used as the adsorption column for dynamic iodine capture with a bed volume of 1490 mL, which is much higher than commercially activated carbons. Overall, this work provides guidance for the development of novel fiber adsorbents for related applications.