Electrochemically activated peroxymonosulfate with mixed metal oxide electrodes for sulfadiazine degradation:...

Electrochemically activated peroxymonosulfate with mixed metal oxide electrodes (EA-PMS-MMO/MMO) is an emerging advanced oxidation process. It performed well on the degradation of sulfadiazine (SDZ), whose removal rate reached 81.13% within 30 min. Both the MMO anode and cathode played an irreplaceable role in PMS activation. HO^•, SO₄^•-, O₂^•- and ¹O₂ were confirmed to be the major reactive species in the system, among which ¹O₂ was the most abundant. The generation mechanism of the reactive species and the overall mechanism of the system were proposed. Four degradation pathways of SDZ were speculated based on density functional theory. The acute and chronic toxicity of SDZ and its degradation intermediates was evaluated by the quantitative structure-activity relationship method, and the overall toxicity was significantly reduced after the degradation by EA-PMS-MMO/MMO. The results show that EA-PMS-MMO/MMO affords a reliable technology for the degradation of organic contaminants and has promising potential for application.