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Updated: Aug 26, 2025

Reductive Electropolymerization of a Vinyl-containing Poly-pyridyl Complex on Glassy Carbon and Fluorine-doped Tin Oxide Electrodes
Published on: January 30, 2015
Nickel-Catalyzed Reductive Dicarbofunctionalization of Vinylarenes Enabled by Electrochemical Process
Pengwei Hu1, Lin Guo1, Lulu Zhao1
1State Key Lab of Urban Water Resource and Environment, School of Science, Harbin Institute of Technology (Shenzhen), Shenzhen 518055, China.
Abstract:
An intermolecular alkene dicarbofunctionalization via electrochemical reduction that combines alkyl and aryl iodides with styrene derivatives was herein reported. The multicomponent reaction exhibited several synthetic advantages including simple operation, wide substrate scope, and convenience of amplification. Mechanistic investigations, including cyclic voltammetry (CV), electron paramagnetic resonance (EPR), and radical trapping reactions, support the electrochemical nickel catalytic cycle and formation of alkyl radical species from alkyl iodides.
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