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Migration of solidification grain boundaries and prediction
Hongmei Liu1,2,3, Shenglu Lu4, Yingbo Zhang5
1School of Materials Science and Engineering, Southwest Jiaotong University, 610031, Chengdu, China. lhm@home.swjtu.edu.cn.
Solidification grain boundary migration (SGBM) decouples boundaries from microsegregation in magnesium-tin alloys. SGBM is independent of cooling rate, depending instead on grain size, offering new control over material properties.
Area of Science:
- Materials Science
- Metallurgy
- Solidification Science
Background:
- Solidification processing is crucial for metal manufacturing, including additive manufacturing.
- Solidification grain boundaries (SGBs) form from the last liquid film between adjacent grains.
- SGB migration (SGBM) decouples SGBs from microsegregation, impacting material properties.
Purpose of the Study:
- To investigate the features of SGBM in magnesium-tin alloys.
- To develop a theoretical model for SGBM in dilute binary alloys.
- To understand the influence of solute type and content on SGBM.
Main Methods:
- Experimental observation of SGBM in magnesium-tin alloys under varying cooling rates (8-1690 °C/s).
- Development of a theoretical model for SGBM in binary alloys.
- Application and validation of the model across 10 alloy systems.
Main Results:
- SGBM was observed and characterized in magnesium-tin alloys.
- The theoretical model accurately predicted SGBM behavior in various alloys.
- SGBM was found to be independent of cooling rate and time, correlating with grain size.
- SGBM exhibits a tendency for athermal occurrence.
Conclusions:
- SGBM is a significant phenomenon in solidification processing, independent of cooling rate.
- Grain size is a key factor controlling SGBM.
- The developed model provides a framework for predicting and controlling SGBM.
- Findings offer new strategies for optimizing solidification grain structure and material performance, mitigating issues like cracking and corrosion.
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