Active Oxygen Functional Group Modification and the Combined Interface Engineering Strategy for Efficient Hydrogen...

Cathodic catalytic activity and interfacial mass transfer are key factors for efficiently generating hydrogen peroxide (H₂O₂) via a two-electron oxygen reduction reaction (ORR). In this work, a carbonized carboxymethyl cellulose (CMC)-reduced graphene oxide (rGO) synthetic fabric cathode was designed and constructed to improve two-electron ORR activity and interfacial mass transfer. Carbonized CMC exhibits abundant active carboxyl groups and excellent two-electron ORR activity with an H₂O₂ selectivity of approximately 87%, higher than that of rGO and other commonly used carbonaceous catalysts. Carbonizing CMC and the agglomerates formed from it restrain the restacking of rGO sheets and thus create abundant meso/macroporous channels for the interfacial mass transfer of oxygen and H₂O₂. Thus, the as-constructed carbonized CMC-rGO synthetic fabric cathode exhibits exceptional H₂O₂ electrosynthesis performance with 11.94 mg·h^-1·cm^-2 yield and 82.32% current efficiency. The sufficient active sites and mass-transfer channels of the cathode also ensure its practical application performance at high current densities, which is further illustrated by the rapid organic pollutant degradation via the H₂O₂-based electro-Fenton process.