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Updated: Aug 26, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Photoinduced Nickel-Catalyzed Carbon-Heteroatom Coupling
Hang Luo1, Guohua Wang1, Yunhui Feng1
1Department Zhang Dayu School of Chemistry, Dalian University of Technology, 116024, Dalian, Liaoning, P. R. China.
Abstract:
Herein, we report visible light-promoted single nickel catalysis for diverse carbon-heteroatom couplings under mild conditions. This mild, general, and robust method to couple diverse nitrogen, oxygen, and sulfur nucleophiles with aryl(heteroaryl)/alkenyl iodides/bromides exhibits a wide functional group tolerance and is applicable to late-stage modification of pharmaceuticals and natural products. On the base of preliminary mechanistic studies, a NiI /NiIII cycle via the generation of active NiI complexes that appear from homolysis of NiII -I rather than NiII -aryl bond was tentatively proposed.
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