Nanosheets of In₂S₃/S-C₃N₄-Dots for Solar Water-Splitting in Saline Water

Hydrogen generation from splitting of water under the photoelectrochemical (PEC) pathway is considered as the most promising strategy for covering the upcoming fuel crisis by taking care of all environmental issues. In this context, In₂S₃ can be explored as it is a visible light-active semiconductor with an appropriate band alignment with the water redox potential. Herein, In₂S₃ nanosheets are developed by the chemical method. The nanosheets of In₂S₃ absorb high visible light due to the manifold inside scattering and reflection. The PEC activity of In₂S₃ is enhanced because of the increase in the light absorbance of the materials. In the present work, at 1.18 V versus RHE in 3.5 wt % NaCl, a maximum 2.07 mA/cm² photocurrent density can be achieved by In₂S₃ nanosheets. However, In₂S₃ suffers strongly due to photo-corrosion. To improve the efficacy of the In₂S₃ nanosheets in saline water, the charge-carrier transportation ability of In₂S₃ is aimed to increase by decorating S-C₃N₄-dots on In₂S₃. The heterostructure of type-II is developed by sensitization of S-C₃N₄-dots on In₂S₃. It increases both the transportation of charge carriers as well as separation. In the heterostructure, the transient decay time (τ) increases, which indicates a decrease in photogenerated charge-carrier recombination. S-C₃N₄-dots also act as an optical antenna and increase the range of visible light absorbance of In₂S₃. The heterostructure can generate ∼2.38-fold higher photocurrent density of 1.18 V versus RHE in 3.5 wt % NaCl. The photoconversion efficiency of the heterostructure is 0.88% at 0.95 V versus RHE. The nanosheets of In₂S₃ and In₂S₃/S-C₃N₄-dots are stable, and photocurrent density is measured up to 2700 s under continuous back-illumination conditions.