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Updated: Aug 26, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
NiH-catalyzed C(sp3)-Si coupling of alkenes with vinyl chlorosilanes
Huanhuan Cui1, Changhao Niu1, Mimi Xing1
1Institute of Molecular Plus, Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University, Weijin Rd. 92, Tianjin 300072, China. chunzhang@tju.edu.cn.
Abstract:
A novel NiH-catalyzed highly regioselective coupling of alkenes with vinyl chlorosilanes, constructing C-Si bonds, is developed. Under mild reaction conditions, a series of benzyl organosilanes with various functional groups could be accessed. Further synthetic studies illustrate that the products of this chemistry could be used as versatile precursors to prepare complicated organosilicon compounds. Moreover, the NiH-catalyzed mechanism of the present transformation was proposed based on control experiments.
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