Development and characteristics of infrared gradient refractive index chalcogenide glasses by hot pressing

Compared with ordinary uniform lenses, the length and refractive index distribution of gradient refractive index (GRIN) lenses can effectively correct aberration and chromatic aberration. This advantage makes the miniaturization, integration, and lens lightweight possible. Although the visible GRIN lenses based on silicate glass are widely used, the infrared GRIN lenses based on chalcogenide glass are still elusive. This paper introduces a new method for preparing this kind of lens by hot pressing sintering diffusion of chalcogenide glasses. A series of chalcogenide glasses Ge₁₀As₂₂Se_68-xS_x (x = 4, 7, 10, 14, 24, 28, 34 mol%) with refractive index range from 2.37 to 2.57 (n@8 µm) and similar glass transition temperature (ΔT_g < 10℃) were prepared by melt quenching. The relationship between Raman peaks and the refractive index of glasses was studied. Furthermore, the refractive index profile formed by elemental diffusion was characterized by Raman signals. The results show that the diffusion length reaches more than 290 µm, and larger diffusion distances can be achieved by stacking multiple layers. The obtained GRIN glass maintains good transmittance in the whole atmospheric window of 2 ∼ 12 µm.