Heterostructures Stimulate Electric-Field to Facilitate Optimal Zn²⁺ Intercalation in MoS₂ Cathode

The electric-field effect is an important factor to enhance the charge diffusion and transfer kinetics of interfacial electrode materials. Herein, by designing a heterojunction, the influence of the electric-field effect on the kinetics of the MoS₂ as cathode materials for aqueous Zn-ion batteries (AZIBs) is deeply investigated. The hybrid heterojunction is developed by hydrothermal growth of MoS₂ nanosheets on robust titanium-based transition metal compound ([titanium nitride, TiN] and [titanium oxide, TiO₂ ]) nanowires, denoted TNC@MoS₂ and TOC@MoS₂ NWS, respectively. Benefiting from the heterostructure architecture and electric-field effect, the TNC@MoS₂ electrodes exhibit an impressive rate performance of 200 mAh g^-1 at 50 mA g^-1 and cycling stability over 3000 cycles. Theoretical studies reveal that the hybrid architecture exhibits a large-scale electric-field effect at the interface between TiN and MoS₂ , enhances the adsorption energy of Zn-ions, and increases their charge transfer, which leads to accelerated diffusion kinetics. In addition, the electric-field effect can also be effectively applied to TiO₂ and MoS₂ , confirming that the concept of heterostructures stimulating electric-field can provide a relevant understanding for the architecture of other cathode materials for AZIBs and beyond.