Engineering the electronic structure of high performance FeCo bimetallic cathode catalysts for microbial fuel cell...

The development of high-performance, strong-durability and low-cost cathode catalysts toward oxygen reduction reaction (ORR) is of great significance for microbial fuel cells (MFCs). In this study, a series of bimetallic catalysts were synthesized by pyrolyzing a mixture of g-C₃N₄ and Fe, Co-tannic complex with various Fe/Co atomic ratios. The initial Fe/Co atomic ratio (3.5:0.5, 3:1, 2:2, 1:3) could regulate the electronic state, which effectively promoted the intrinsic electrocatalytic ORR activity. The alloy metal particles and metal-N_x sites presented on the catalyst surface. In addition, N-doped carbon interconnected network consisting of graphene-like and bamboo-like carbon nanotube structure derived from g-C₃N₄ provided more accessible active sites. The resultant Fe₃Co₁ catalyst calcined at 700 °C (Fe₃Co₁-700) exhibited high catalytic performance in neutral electrolyte with a half-wave potential of 0.661 V, exceeding that of the commercial Pt/C (0.6 V). As expected, the single chamber microbial fuel cell (SCMFC) with 1 mg/cm² loading of Fe₃Co₁-700 catalyst as the cathode catalyst afforded a maximum power density of 1425 mW/m², which was 10.5% higher than commercial Pt/C catalyst with the same loading (1290 mW/m²) and comparable to the Pt/C catalyst with 2.5 times higher loading ( 1430 mW/m²). Additionally, the Fe₃Co₁-700 also displayed better long-term stability over 1100 h than the Pt/C. This work provides an effective strategy for regulating the surface electronic state in the bimetallic electro-catalyst.