Diatomaceous Earth-Lightweight Pozzolanic Admixtures for Repair Mortars-Complex Chemical and Physical Assessment

The presented research is focused on the complex assessment of three different types of diatomaceous earth and evaluation of their ability for application as pozzolana active admixtures applicable in the concrete industry and the production of repair mortars applicable for historical masonry. The comprehensive experimental campaign comprised chemical, mineralogical, microstructural, and physical testing of raw materials, followed by the analyses and characterization of pozzolanic activity, rheology and heat evolution of fresh blended pastes, and testing of macrostructural and mechanical parameters of the hardened 28-days and 90-days samples. The obtained results gave evidence of the different behavior of researched diatomaceous earth when mixed with water and Portland cement. The differences in heat evolution, initial and final setting time, porosity, density, and mechanical parameters were identified based on chemical and phase composition, particle size, specific surface, and morphology of diatomaceous particles. Nevertheless, the researched mineral admixtures yielded a high strength activity index (92.9% to 113.6%), evinced their pozzolanic activity. Three fundamental factors were identified that affect diatomaceous earth's contribution to the mechanical strength of cement blends. These are the filler effect, the pertinent acceleration of OPC hydration, and the pozzolanic reaction of diatomite with Portland cement hydrates. The optimum replacement level of ordinary Portland cement by diatomaceous earth to give maximum long-term strength enhancement is about 10 wt.%., but it might be further enhanced based on the properties of pozzolan.