Conductometric ppb-Level CO Sensors Based on In₂O₃ Nanofibers Co-Modified with Au and Pd Species

Carbon monoxide (CO) is one of the most toxic gases to human life. Therefore, the effective monitoring of it down to ppb level is of great significance. Herein, a series of In₂O₃ nanofibers modified with Au or Pd species or simultaneous Au and Pd species have been prepared by electrospinning combined with a calcination process. The as-obtained samples are applied for the detection of CO. Gas-sensing investigations indicate that 2 at% Au and 2 at% Pd-co-modified In₂O₃ nanofibers exhibit the highest response (21.7) to 100 ppm CO at 180 °C, and the response value is ~8.5 times higher than that of pure In₂O₃ nanofibers. More importantly, the detection limit to CO is about 200 ppb with a response value of 1.23, and is obviously lower than that (6 ppm) of pure In₂O₃ nanofibers. In addition, the sensor also shows good stability within 19 days. These demonstrate that co-modifying In₂O₃ nanofibers with suitable amounts of Pd and Au species might be a meaningful strategy for the development of high-performance carbon monoxide gas sensors.