The Influence of Electrode Thickness on the Structure and Water Splitting Performance of Iridium Oxide Nanostructured...

For a safe environment, humanity should be oriented towards renewable energy technology. Water splitting (WS), utilizing a photoelectrode with suitable thickness, morphology, and conductivity, is essential for efficient hydrogen production. In this report, iridium oxide (IrO_x) films of high conductivity were spin-cast on glass substrates. FE-SEM showed that the films are of nanorod morphology and different thicknesses. UV-Vis spectra indicated that the absorption and reflectance of the films depend on their thickness. The optical band gap (E_g) was increased from 2.925 eV to 3.07 eV by varying the spin speed (SS) of the substrates in a range of 1.5 × 10³-4.5 × 10³ rpm. It was clear from the micro-Raman spectra that the films were amorphous. The E_g vibrational mode of Ir-O stretching was red-shifted from 563 cm^-1 (for the rutile IrO₂ single crystal) to 553 cm^-1. The IrO_x films were used to develop photoelectrochemical (PEC) hydrogen production catalysts in 0.5M of sodium sulfite heptahydrate Na₂SO₃·7H₂O (2-electrode system), which exhibits higher hydrogen evaluation (HE) reaction activity, which is proportional to the thickness and absorbance of the used IrO_x photocathode, as it showed an incident photon-to-current efficiency (IPCE%) of 7.069% at 390 nm and -1 V. Photocurrent density (Jph = 2.38 mA/cm² at -1 V vs. platinum) and PEC hydrogen generation rate (83.68 mmol/ h cm² at 1 V) are the best characteristics of the best electrode (the thickest and most absorbent IrO_x photocathode). At -1 V and 500 nm, the absorbed photon-to-current conversion efficiency (APCE%) was 7.84%. Electrode stability, thermodynamic factors, solar-to-hydrogen conversion efficiency (STH), and electrochemical impedance spectroscopies (EISs) were also studied.