Cd₃P₂/Zn₃P₂ Core-Shell Nanocrystals: Synthesis and Optical Properties

II-V semiconductor nanocrystals such as Cd₃P₂ and Zn₃P₂ have enormous potential as materials in next-generation optoelectronic devices requiring active optical properties across the visible and infrared range. To date, this potential has been unfulfilled due to their inherent instability with respect to air and moisture. Core-shell system Cd₃P₂/Zn₃P₂ is synthesized and studied from structural (morphology, crystallinity, shell diameter), chemical (composition of core, shell, and ligand sphere), and optical perspectives (absorbance, emission-steady state and time resolved, quantum yield, and air stability). The improvements achieved by coating with Zn₃P₂ are likely due to its identical crystal structure to Cd₃P₂ (tetragonal), highlighting the key role crystallographic concerns play in creating cutting edge core-shell NCs.