Effect of Al₂O₃ on Nanostructure and Ion Transport Properties of PVA/PEG/SSA Polymer Electrolyte Membrane

Polymer electrolyte membrane (PEM) fuel cells have the potential to reduce our energy consumption, pollutant emissions, and dependence on fossil fuels. To achieve a wide range of commercial PEMs, many efforts have been made to create novel polymer-based materials that can transport protons under anhydrous conditions. In this study, cross-linked poly(vinyl) alcohol (PVA)/poly(ethylene) glycol (PEG) membranes with varying alumina (Al₂O₃) content were synthesized using the solvent solution method. Wide-angle X-ray diffraction (XRD), water uptake, ion exchange capacity (IEC), and proton conductivity were then used to characterize the membranes. XRD results showed that the concentration of Al₂O₃ affected the degree of crystallinity of the membranes, with 0.7 wt.% Al₂O₃ providing the lowest crystallinity. Water uptake was discovered to be dependent not only on the Al₂O₃ group concentration (SSA content) but also on SSA, which influenced the hole volume size in the membranes. The ionic conductivity measurements provided that the samples were increased by SSA to a high value (0.13 S/m) at 0.7 wt.% Al₂O₃. Furthermore, the ionic conductivity of polymers devoid of SSA tended to increase as the Al₂O₃ concentration increased. The positron annihilation lifetimes revealed that as the Al₂O₃ concentration increased, the hole volume content of the polymer without SSA also increased. However, it was densified with SSA for the membrane. According to the findings of the study, PVA/PEG/SSA/0.7 wt.% Al₂O₃ might be employed as a PEM with high proton conductivity for fuel cell applications.