Stress Relaxation Behavior of Poly(Methyl Methacrylate)/Graphene Composites: Ultraviolet Irradiation

The graphene/poly (methyl methacrylate) (PMMA) composites are a promising candidate for electronic, optoelectrical, and environmental applications. Understanding the mechanical degradation of PMMA-based materials is of practical importance in improving the reliability and lifespan of the associated structures and systems. In this study, we investigate the effects of functionalized graphene (FG) and UV irradiation on the stress-relaxation of PMMA. Uniaxial tensile and stress -relaxation tests are performed to evaluate the mechanical properties of the composites. The mechanical strength and elongation at the break increase with the graphene concentration but decrease with the increase of the irradiation dose. Raman spectroscopy and intrinsic viscosity measurement are applied to examine the root cause of the degradation in the composites. UV irradiation leads to polymer chain scission and loss of molecular weight. The Kelvin representation of the standard linear solid model (SLSM) is used to describe the stress-relaxation curves of the composites. The value of the elastic modulus in the Kelvin element decreases with the increase in temperature. The viscosity follows the Arrhenius equation. The activation energy of viscosity increases with the increasing FGs concentration because the FGs hinder the chain motion of PMMA. However, UV irradiation makes chain scission of PMMA/FGs composite so that the polymer chain moves more easily and the activation energy of stress relaxation lowers. The steady-state stress follows the van 't Hoff equation that stress relaxation is an exothermal deformation process. Although Maxwell's representation of SLSM is mathematically identical to the Kelvin representation of SLSM, the former cannot interpret the stress-relaxation behavior of PMMA/FGs composite, which is against the concept of Young's modulus as a decreasing temperature function.