Facile hydrothermal synthesis of layered 1T' MoTe₂ nanotubes as robust hydrogen evolution electrocatalysts

Layered transition metal dichalcogenides (TMDs), such as molybdenum ditelluride (MoTe₂), have attracted much attention because of their novel structure-related physicochemical properties. In particular, semi-metallic-phase MoTe₂ (1T') is considered as a competitive candidate for low-cost electrocatalysts for water splitting. However, there are few reports on the simple hydrothermal synthesis of MoTe₂ nanostructures compared with other layered TMDs. In this study, a facile one-step hydrothermal process was developed for the fabrication of layered MoTe₂, in which uniform nanotubes with a few layers of 1T' MoTe₂ were fabricated at a lower temperature for the first time. The as-obtained MoTe₂ nanotubes were fully characterized using different techniques, which revealed their structure and indicated the presence of layered 1T' nanocrystals. The efficient activity of MoTe₂ nanotubes for the electrocatalytic hydrogen evolution reaction (HER) in 0.5 M H₂SO₄ was demonstrated by the small Tafel slope of 54 mV/dec^-1 and endurable ability, which is attributed to the abundant active sites and remarkable conductivity of 1T' MoTe₂ with a few-layer feature. This provides a facile method for the design and construction of efficient layered MoTe₂ based electrocatalysts.