Identifying the geochemical evolution and controlling factors of the shallow groundwater in a high fluoride area,...

Understanding how groundwater is formed and evolves is critical for water resource exploitation and utilization. In this study, hydrochemistry and stable isotope tracing techniques were adopted to determine the key factors influencing groundwater chemical evolution in Feng County. A total of fourteen wells and five surface water samples were investigated in November 2021. The δD and δ¹⁸O compositions show that both surface water and groundwater are recharged from atmospheric precipitation. The dominating order of cations and anions in groundwater appears to be Na⁺ > Mg²⁺ > Ca²⁺ > K⁺ and HCO₃^- > SO₄^2- > Cl^- > NO₃^- > F^-, respectively. The groundwater hydrochemical facies are mainly characterized by HCO₃-Ca-Mg and SO₄-Cl-Na types. The chemical evolution of groundwater is dominated by water-rock interaction and cation exchange reactions. The major ions in groundwater are mainly controlled by various geogenic processes including halite, gypsum, calcite, dolomite, Glauber's salt, feldspar, and fluorite dissolution/precipitation. Furthermore, the abundant fluoride-bearing sediments, together with low Ca²⁺, promote the formation of high F^- groundwater. Approximately 85.7% and 28.6% of groundwater samples exceeded the permissible limit for F^- and NO₃^- respectively. Apart from geogenic F^-, human interventions (i.e., industrial fluoride-containing wastewater discharge and agricultural phosphate fertilizer uses) also regulate the F^- enrichment in the shallow groundwater. Nitrate pollution of the groundwater may be attributed to domestic waste and animal feces. Our findings could provide valuable information for the sustainable exploitation of groundwater in the study area and the development of effective management strategies by the authorities.