Perovskite-Based Electrocatalysts for Cost-Effective Ultrahigh-Current-Density Water Splitting in Anion Exchange...

Development of cost-effective water splitting technology that allows low-overpotential operation at high current density with non-precious catalysts is the key for large-scale hydrogen production. Herein, it is demonstrated that the versatile perovskite-based oxides, usually applied for operating at low current density and room temperature in alkaline solution, can be developed into low-cost, highly active and durable electrocatalysts for operating at high current densities in a zero-gap anion exchange membrane electrolyzer cell (AEMEC). The composite perovskite with mixed phases of Ruddlesden-Popper and single perovskite is applied as the anode in AEMEC and exhibits highly promising performance with an overall water-splitting current density of 2.01 A cm^-2 at a cell voltage of only 2.00 V at 60 °C with stable performance. The elevated temperature to promote anion diffusion in membrane boosts oxygen evolution kinetics by enhancing lattice-oxygen participation. The bifunctionality of perovskites further promises the more cost-effective symmetrical AEMEC configuration, and a primary cell with the composite perovskite as both electrodes delivers 3.00 A cm^-2 at a cell voltage of only 2.42 V. This work greatly expands the use of perovskites as robust electrocatalysts for industrial water splitting at high current density with great practical application merit.