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Updated: Aug 25, 2025

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
Self-assembly of a novel multicomponent polyoxometalate-based tetrahedral supercluster with high catalytic activity
Xiaodong Liu1, Na Xu1, Xiaohui Liu1
1College of Chemistry and Materials Engineering, Bohai University, Liaoning Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Jinzhou, 121013, P. R. China. xun872@bhu.edu.cn.
Abstract:
A glamorous polyoxometalate (POM)-based macromolecule containing a tetrahedral supercluster (Hbiz)12[(P2Co2MoV4O8)2(P2MoV2O8)4(Pb⊂P6Co2MoV2MoVI14O73)4]·ca.129H2O (1) was in situ self-assembled from three novel components, [Pb⊂P6Co2Mo16O73]8- (P6Co2Mo16), [P2MoV2O8]4+ (P2Mo2) and [P2Co2MoV4O8]18+ (P2Co2Mo4), respectively. To our knowledge, 1 represents the first tetrahedral supercluster containing the basket-like POM structure. Besides, macromolecule 1 exhibits high catalytic activity and reusability for the oxidation of thioethers to sulfoxides.
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