A multifunctional heterogeneous superwettable coating for water collection, oil/water separation and oil absorption

Herein, inspired by desert beetles, we fabricated a multifunctional heterogeneous superwettable coating (MHSC) for water collection and oily wastewater cleanup. The selective modifications of 1-octadecanethiol (ODT) treated CoO and P25 TiO₂ nanoparticles (NPs) were prepared, so hydrophobic CoO NPs and superhydrophilic P25 NPs were combined on the MHSC, showing the water contact angle (WCA) of 156.5° and rolling-off angle (RA) of 6.4°. With the aid of waterborne polyurethane (WPU), five kinds of substrates (i.e., glass slide, dish, wood, fabric, sponge) spray-coated by MHSC displayed high-efficiency water collection rates (WCRs) of 18.1 ± 0.7 mg min^-1 cm^-2. Moreover, MHSC coated fabric manifested robust oil/water separations with separation efficiencies (SEs) > 99.7 % and fluxes ranged from 9.7 to 11.0 L m^-2 s^-1. Efficient oil sorption from oily water was obtained by MHSC coated sponge with oil absorption capacities (OACs) of 6.5-29.5 g g^-1. Further, even dealt with the treatments of mechanical destructions, extreme temperature and UV illumination, the coated materials remained stable performances.