Edge-Nitrogen Enriched Porous Carbon Nanosheets Anodes with Enlarged Interlayer Distance for Fast Charging Sodium-Ion...

The application of nitrogen-doped porous carbon for sodium-ion batteries (SIBs) has attracted tremendous attention. Herein, a series of edge-nitrogen enriched porous carbon nanosheets (ENPCNs) are synthesized by annealing g-C₃ N₄ and glucose in a sealed graphite crucible at different temperatures (T = 700, 800, and 900 °C). Surprisingly, under the closed thermal treatment condition, the ENPCNs-T possess a high N-doping level (>12.62 at%) and different carbon interlayer distance ranging from 0.429 to 0.487 nm. By correlating the carbon interlayer distance with the N configurations of ENPCNs-T materials, a reasonable perception of the important influence of pyrrolic N on the increase of carbon interlayer distance is proposed. When applied as anode materials for SIBs, the ENPCNs-800 exhibits a remarkable capacity (294.1 mAh g^-1 at 0.1 A g^-1 ), excellent rate performance (132.8 mAh g^-1 at 10 A g^-1 ), and outstanding cycle life (180.6 mAh g^-1 at 1 A g^-1 after 1000 cycles with a capacity retention of 104.7%). Meanwhile, the characterizations of cyclic voltammetry, galvanostatic intermittent titration technique, and electrochemical impedance spectroscopy demonstrate that the edge-nitrogen doping and enlarged carbon interlayer distance improve the capacity and fast charging performance of ENPCNs-800. Considering the detailed investigation of the Na⁺ storage mechanism and excellent electrochemical performance of ENPCNs-800, this work can pave a new avenue for the research of SIBs.