Constructing Z-scheme g-C₃N₄/TiO₂ heterostructure for promoting degradation of the hazardous dye pollutants

The use of dyes and segments has increased widely in recent years, but it poses a serious health risk to ecosystems. In this work, TiO₂ and two-dimensional g-C₃N₄ nanosheets (g-CN) were fabricated through co-precipitation and thermal polymerization technique, respectively. The g-CN-TiO₂ photocatalyst (1: 3, 2: 2, 3: 1) in various weight percentages was prepared using a simple impregnation process. The photocatalytic behaviour of the g-CN, TiO₂ NPs, and different weight percentages of g-CN-TiO₂ photocatalyst was evaluated against methylene blue (MB) dye under UV-visible light illumination. Compared to pristine and other weight percentages of the g-CN-TiO₂ nanocomposite, the optimized g-CN-TiO₂ nanocomposite (3:1) showed promoted performance against MB dye. The enriched catalytic efficiency can be accredited to the low amount of TiO₂ nanoparticles deposited on gCN nanosheets, possibly due to the boosted transport properties of the electron-hole pairs. The enriched photocatalytic behaviour can be attributed to the development of the Z-scheme system between TiO₂ and g-CN. The current study is an outstanding demonstration of the development of maximum catalytic efficiency for destroying hazardous chemical dyes.