Synthesis and performance evaluation of copper and magnesium-based metal organic framework supported ionic liquid...

The CO₂ emission is enhancing drastically because of the continuous emission from industries and transport sector. Although the CO₂ emission had decreased in the first half of 2020 by 8.8% due to COVID-19 restrictions however, it is again on the rise and it might exceed the estimated level in 2030. The current methods used for CO₂ separation have serious operational and environmental constraints. To overcome these problems we have devised a supported ionic liquid membrane (SILM) incorporated with the blend of bimetallic metal-organic framework (MOF) of copper and magnesium ions (Cu_xMg_x) and Trihexyltetradecylphosphonium chloride [P₆₆₆₁₄] [Cl] ionic liquid (IL). Cu_xMg_x MOF were synthesized and characterized using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD), and energy dispersive X-ray analysis (EDX). Cu_xMg_x MOF with [P₆₆₆₁₄] [Cl] IL were immobilized on a flat sheet of polytetrafluoroethylene (PTFE) membrane. Single gas permeation tests of membranes loaded with 0.2/0.8 wt/wt% MOF/IL solution showed the highest CO₂ permeability of 2937 Barrer and CO₂/N₂ selectivity of 33.26. The performance of SILM was also investigated with different water loadings of (30 wt % and 50 wt %) in addition to MOF/IL solution and at different feed pressure varying from 0.5 to 2 bars. Membranes showed enhancement in CO₂ permeability to 3738 and 4628 Barrer whereas CO₂/N₂ selectivity decreased to 23.53 and 21.8 with membranes loaded with 30 and 50 wt % water, respectively, at a feed pressure of 2 bar. The gas permeation results show that the incorporation of Cu_xMg_x MOF with IL in polymeric membrane enhances the CO₂/N₂ separation under humid conditions but slightly decreases CO₂/N₂ selectivity with an increase in feed pressure. The SILM synthesized in this research is highly viable for industrial flue gases because of the incorporation of phosphonium-based ILs that have high thermal stability.