Related Experiment Video
Updated: Aug 24, 2025
![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Effect of the dangling aromatic ring on neutral luminescent bis(phosphine) Cu(i)/Ag(i) complexes with the asymmetric
Jing Xiang1, Li-Xin Wang1, Xu Zhang1
1College of Chemistry and Environmental Engineering, Yangtze University Jingzhou 434020 Hubei P. R. China zhangxu@yangtzeu.edu.cn xiangjing@yangtzeu.edu.cn.
Abstract:
A series of neutral luminescent bis(phosphine) Cu(i) complexes of pyridyl-tetrazolate ligands (L1-L3) with the general formula [CuI(L )(P^P)] (1-6) were synthesized, which have been well characterized by IR, UV/vis, CV, 1H NMR and 31P NMR. For comparison, an Ag(i) complex [AgI(L2)(PPh3)2] (7) was also synthesized. The crystal structures of 2 and 7 have been further determined by X-ray crystallography. All these Cu(i) compounds show bright luminescence in the solid state with photoluminescence quantum yields (PLQYs) in the range of 25.8% to 85.0%. More interestingly, the Cu(i) complexes bearing an additional dangling aromatic ring on the diimine ligands exhibit enhanced luminescent performance in various solutions and their PLQYs are significantly higher than those of related Cu(i) complexes without steric protection. Compared with 1, the Cu(i) complexes with an additional dangling tetrazole moiety show a significant solvatochromic effect, which is uncommon for luminescent Cu(i) complexes. Moreover, [CuI(L2)(PPh3)2] (2) was further designed as an OLED material, which showed a high external quantum efficiency of 7.7%.
More Related Videos
14:11Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach
Published on: June 10, 2021
07:20Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
Related Concept Videos
Variables Affecting Phosphorescence and Fluorescence
π Electron Effects on Chemical Shift: Aromatic and Antiaromatic Compounds
Aryldiazonium Salts to Azo Dyes: Diazo Coupling
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
Valence Bond Theory
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...