Thermoplasmonics Decontamination of Respirators Face Masks Using Silver Nanoparticles: A New Weapon in the Fight...

The current COVID-19 pandemic has resulted in an urgent need for methods to decontaminate respirators masks for reuse while keeping them intact and functional. The severe shortage of professional masks such as N95 and FFP2 has necessitated their reuse over long periods. A very promising method is the pasteurization of these masks by thermoplasmonic heat generated by plasmonics nanoparticles when they are irradiated by light. Under illumination at its plasmonic resonance, a metal nanoparticle features enhanced light absorption, turning it into an ideal nano-source of heat, remotely controllable using light. In this work, we propose a numerical study based on the finite element method (FEM) of the thermoplasmonic properties of silver nanoparticles (AgNPs) decorating polypropylene (PP) fibers which is a basic material for the manufacture of these masks. The surface plasmon resonance (SPR) of these nanostructures was investigated through the computation of the complex effective dielectric permittivity and the absorption cross section in the near UV-visible (NUV-Vis) range. First, the SPR characteristics of AgNPs for different morphologies are determined from the absorption spectra, including the SPR-peak position λ_max and the electric field enhancement. Second, we determine the power absorbed by an individual AgNP of different morphologies. From this, we calculate the internal temperature increase of the particle at the plasmonic resonance. The last step is devoted to the determination of the temperature profile in the surrounding medium in order to better understand and design the plasmon-assisted heating processes at the nanometric scale.