Study on the catalytic degradation of Acid Orange 7 and the potential mechanism by ferrous-percarbonate

Factors affecting the degradation of Acid Orange 7 (AO7) were evaluated and optimized when ferrous was used to catalyze percarbonate in the present study. The optimized conditions included the initial pH values ranging from 3 to 11 for AO7 solution, the initial level of AO7, sodium percarbonate (SPC), and Fe²⁺ . Some ions and natural organic materials, which commonly exist in natural water, were also tested to evaluate their potential impacts on the degradation of AO7. The degradation efficiency of AO7 was up to 95% under the optimized test conditions, where the ferrous/percarbonate/AO7 molar ratio was 15/10/1 in the 0.285 mmol/l AO7 aqueous solution. The presence of Cl^- , SO₄ ^2- , NO₃ ^- , Na⁺ , and Mg²⁺ did not affect the removal of AO7. The addition of HCO₃ ^- significantly inhibited its removal, even when the concentration of HCO₃ ^- was low to 0.6 mmol/l. A slight inhibition effect was observed when the added concentration of humic acid ranged from 0.5 to 5 mg/l, whereas the residue of AO7 was significantly enhanced when the level of humic acid was continually increased from 50 to 100 mg/l. Hydroxyl radicals (•OH) were the main reactive intermediates controlling the oxidation of AO7 in the present Fe²⁺ /SPC system. The produced intermediates through the degradation of AO7 were identified to include 2-coumaranone, 2-naphthol, phthalic acid, phthalimide, N-methylnaphthylamine, and 2-methylphenol. The proposed degradation pathways are consistent with the radical formation and the identified intermediates. PRACTITIONER POINTS: The ferrous/percarbonate system can remove 95% of AO7 under the optimized conditions. AO7 removal was inhibited by adding HCO₃ ^- and humic acid, but not affected by Cl^- , SO₄ ^2- , NO₃ ^- , Na⁺ , and Mg²⁺ . Hydroxylation, ring opening, and mineralization driven by the generated hydroxyl radicals were derived as the major processes for degrading AO7.