The ground-level ozone concentration in forest and urban environments in central Slovakia

This paper analyses data by summarising the concentration values of ground-level ozone (GLO). The study area is situated in central Slovakia and is part of the Western Carpathians. These measurements were carried out between 2015 and 2020, implementing Werner's method working with passive samplers. The highest average and the highest absolute GLO deposition values were 30.93 ppb and 61.06 ppb, respectively, recorded in August 2015 in the forest in the Kremnické vrchy Mts. The lowest average GLO value in the whole measuring period was 17.72 ppb, measured in the town of Zvolen; the absolute minimum was 4.43 ppb, recorded in April 2016 on an open plot in the Kremnické vrchy Mts. The GLO formation over the study area has not yet reached a steady rate. Since 2007, the developmental trend has been increasing. Statistically significant differences in GLO concentrations were confirmed between the localities with different airborne pollutions. However, the analysis of the existing ozone concentration values showed considerable differences, especially related to the time pattern. The spatial variability was equalised. The extreme values, while remarkable, were dangerous, especially in the forest stands in the Kremnické vrchy Mts., where they were 14 times above the critical level of 32.5 ppb O₃. The dominant factor influencing the GLO concentration was global radiation. The effects of average temperature and rainfall total were less important.