Synthesis of Gold Nanoparticles from Gold Coatings Recovered from E-Waste Processors

This work presents the synthesis of Au nanoparticles from gold coatings recovered from processor pins with minimal waste generation. The process consisted of four main steps: (1) physical recovery of pins, (2) recovery of gold coatings by acid digestion, (3) synthesis of HAuCl₄ under mild conditions and, (4) synthesis of Au nanoparticles by the Turkevich method. The small dimensions of Au coatings allowed the synthesis of HAuCl₄ with lower amounts of HCl_conc and HNO_3conc than those used with aqua regia. This method has significant advantages, such as lower NO_2(g) emission, easy post-treatment and purification, low synthesis cost and high yields. Gold nanoparticles synthesized from HAuCl₄ were characterized by transmission electron microscopy (TEM) and UV-Vis spectroscopy. Size distribution analysis showed particles 14.23 nm in length and 12.05 nm in width, while absorption spectra showed a surface plasmon located at 523 nm; these characteristics were very similar to those observed with Au nanoparticles obtained with Aldrich's reagent. It is suggested that recycling procedures can be improved by taking into account the size and shape of the metals to be recovered, thus introducing a new field of research known as hydronanometallurgy.