Related Experiment Video

Updated: Aug 23, 2025

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Triflamidation of Allyl-Containing Substances:Unusual Dehydrobromination vs. Intramolecular Heterocyclization

Anton S Ganin1, Mikhail Yu Moskalik1, Ivan A Garagan1

  • 1A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Division of the Russian Academy of Sciences, 1 Favorsky Street, 664033 Irkutsk, Russia.

Molecules (Basel, Switzerland)
|October 27, 2022
PubMed
Summary

This study details the synthesis of halogen-substituted amidines from allyl compounds and triflamide. Brominated amidines are key intermediates, yielding conjugated systems and imidazolidines.

Keywords:
allyl cyanideallyl halidesheterocyclizationoxidative bromotriflamidationsolvent interceptiontriflamide

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