Temperature Dependence of Electrical Resistance in Carbon Nanotube Composite Film during Curing Process

Carbon nanotube (CNT) film possesses excellent mechanical and piezoresistivity, which may act as a sensor for process monitoring and reinforcement of the final composite. This paper prepared CNT/epoxy composite film via the solution dipping method and investigated the electrical resistance variation (ΔR/R₀) of CNT/epoxy composite film during the curing process. The temperature dependence of electrical resistance was found to be closely related to resin rheological properties, thermal expansion, and curing shrinkage. The results show that two opposing effects on electrical resistivity occur at the initial heating stage, including thermal expansion and condensation caused by the wetting tension of the liquid resin. The lower resin content causes more apparent secondary impregnation and electrical resistivity change. When the resin viscosity remains steady during the heating stage, the electrical resistance increases with an increase in temperature due to thermal expansion. Approaching gel time, the electrical resistance drops due to the crosslink shrinkage of epoxy resin. The internal stress caused by curing shrinkage at the high-temperature platform results in an increase in electrical resistance. The temperature coefficient of resistance becomes larger with an increase in resin content. At the isothermal stage, an increase in ΔR/R₀ value becomes less obvious with a decrease in resin content, and ΔR/R₀ even shows a decreasing tendency.