Ni₂P Nanoparticle-Inserted Porous Layered NiO Hetero-Structured Nanosheets as a Durable Catalyst for the...

The electro-oxidation of urea (EOU) is a remarkable but challenging sustainable technology, which largely needs a reduced electro-chemical potential, that demonstrates the ability to remove a notable harmful material from wastewater and/or transform the excretory product of humans into treasure. In this work, an Ni₂P-nanoparticle-integrated porous nickel oxide (NiO) hetero-structured nanosheet (Ni₂P@NiO/NiF) catalyst was synthesized through in situ acid etching and a gas-phase phosphating process. The as-synthesized Ni₂P@NiO/NiF catalyst sample was then used to enhance the electro-oxidation reaction of urea with a higher urea oxidation response (50 mA cm^-2 at 1.31 V vs. RHE) and low onset oxidation potential (1.31 V). The enhanced activity of the Ni₂P@NiO/NiF catalyst was mainly attributed to effective electron transport after Ni₂P nanoparticle insertion through a substantial improvement in active sites due to a larger electrochemical surface area, and a faster diffusion of ions occurred via the interactive sites at the interface of Ni₂P and NiO; thus, the structural reliability was retained, which was further evidenced by the low charge transfer resistance. Further, the Ni₂P nanoparticle insertion process into the NiO hetero-structured nanosheets effectively enabled a synergetic effect when compared to the counter of the Ni₂P/NiF and NiO/NiF catalysts. Finally, we demonstrate that the as-synthesized Ni₂P@NiO/NiF catalyst could be a promising electrode for the EOU in urea-rich wastewater and human urine samples for environmental safety management. Overall, the Ni₂P@NiO/NiF catalyst electrode combines the advantages of the Ni₂P catalyst, NiO nanosheet network, and NiF current collector for enhanced EOU performance, which is highly valuable in catalyst development for environmental safety applications.