Developing an Effective and Durable Film for Marine Fouling Prevention from PDMS/SiO₂ and PDMS/PU with SiO₂...

Polymer film coating with a highly hydrophobic surface property is a practical approach to prevent fouling of any structures in the marine environment without affecting marine microorganisms. The preparation of a polymer coating, from a simple and easy method of solution blending of hydrophobic polydimethylsiloxane elastomer and hydrophilic polyurethane with SiO₂, was carried out in this study, with the aim of improving characteristics, and the coating demonstrated economic feasibility for antifouling application. Incorporation of SiO₂ particles into PDMS and PDMS/PU polymer film improved mechanical properties of the film and the support fabrication of micropatterns by means of a soft lithography process. Observations from field emission scanning electron microscope (FESEM) of the PDMS/SiO₂ composite film revealed a homogeneous morphology and even dispersion of the SiO₂ disperse phase between 1-5 wt.%. Moreover, the PDMS film with 3 wt.% loading of SiO₂ considerably increased WCA to 115.7° ± 2.5° and improved mechanical properties by increasing Young's modulus by 128%, compared with neat PDMS film. Additionally, bonding strength between barnacles and the PDMS film with 3 wt.% of SiO₂ loading was 0.16 MPa, which was much lower than the bonding strength between barnacles and the reference carbon steel of 1.16 MPa. When compared to the previous study using PDMS/PU blend (95:5), the count of barnacles of PDMS with 3 wt.% SiO₂ loading was lower by 77% in the two-week field tests and up to 97% in the eight-week field tests. Subsequently, when PDMS with 3 wt.% SiO₂ was further blended with PU, and the surface modified by the soft lithography process, it was found that PDMS/PU (95:5) with 3 wt.% SiO₂ composite film with micropatterns increased WCA to 122.1° ± 2.9° and OCA 90.8 ± 3.6°, suggesting that the PDMS/PU (95:5) with 3 wt.% SiO₂ composite film with surface modified by the soft lithography process could be employed for antifouling application.