Related Experiment Video
Updated: Aug 23, 2025
Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
In Situ Derived Co2B Nanosheet Array: A High-Efficiency Electrocatalyst for Ambient Ammonia Synthesis via Nitrate
Lisi Xie1, Shengjun Sun2, Long Hu2
1Institute for Advanced Study, Chengdu University, Chengdu610106, Sichuan, China.
None:
Ambient ammonia synthesis via electrochemical nitrate (NO3-) reduction is regarded as a green alternative to the Haber-Bosch process. Herein, we report the in situ derivation of an amorphous Co2B layer on a Co3O4 nanosheet array on a Ti mesh (Co2B@Co3O4/TM) for efficient NH3 production via selective electroreduction of NO3- under ambient conditions. In 0.1 M PBS and 0.1 M NaNO3, Co2B@Co3O4/TM exhibits a maximum Faradaic efficiency of 97.0% at -0.70 V and a remarkable NH3 yield of 8.57 mg/h/cm2 at -1.0 V, with durability for stable NO3--to-NH3 conversion over eight recycling tests and 12 h of electrolysis. Additionally, it can be applied as an efficient cathode material for Zn-NO3- batteries to produce NH3 while generating electricity. The catalytic mechanisms on Co2B@Co3O4 are further revealed by theoretical calculations.
