Hydrogeochemistry and groundwater quality assessment in Ambagarh Chowki, Chhattisgarh, India

The current study was focused on hydrogeochemistry of Ambagarh chowki groundwater. The main aim of the study was to evaluate the water quality for drinking and irrigation uses, hydrogeochemistry of groundwater. For this purpose, various physicochemical parameters like pH, electrical conductivity (EC), total hardness (TH), chloride (Cl^-), fluoride (F^-), calcium (Ca²⁺), magnesium (Mg²⁺), sodium (Na⁺), potassium (K⁺), bicarbonate (HCO₃^-), and sulfate (SO₄^2-) were analyzed. The major dominating ions in groundwater was found as cation Ca²⁺  > Mg²⁺  > Na⁺  > K⁺ and as anions in order of HCO₃^-  > Cl^-  > SO₄^2-  > F^-. The pH of sampled groundwater was ranged from neutral to alkaline in nature (7.0-8.8). Among, all-analyzed parameters in groundwater were safe for drinking purpose except few ions and bicarbonate content was also exceeding the permissible limit which was not suitable for drinking purpose. The potential health hazard element fluoride was varied from 0.1 to 2.2 mg/l and positively associated with the pH, Na⁺, and HCO₃^- content in groundwater. The drinking water quality index (WQI) was fluctuated between 12.22 and 185.56 and reported that most of the groundwater was suitable for drinking purpose except only one sample was unsuitable for drinking. Irrigation water quality assessment of the area was performed by evaluating as sodium adsorption ratio (SAR), permeability index (PI), Kelly ratio (KR), magnesium hazard ratio (MHR), percent sodium (%Na), potential salinity (PS), and residual sodium carbonate (RSC). Whereas most of the groundwater were good and suitable for irrigation use excluding PI (3.70%), MHR (40.74%), RSC (22.22%) and PS (7.41%) were unsuitable for continuous irrigation. Hydrogeochemistry of groundwater evaluated with correlation, Piper, Gibbs, and other geochemical analysis. The Piper trilinear diagram reflects the Ca (Mg)-HCO₃^- type water was mainly contributed approximately 90% of entire sampled groundwater. The different ions in groundwater were originated from the rock water interaction through silicate and carbonate weathering of minerals.