Extremely Reduced Dielectric Constant and Band Gap Enhancement in Few-Layered Tungsten Disulfide Nanosheets

Highly crystalline few-layered tungsten disulfide (WS₂) nanosheets were synthesized via a cost-effective, low-temperature hydrothermal route. X-ray diffraction and HR-TEM analysis confirmed the formation of hexagonal nanosheets with thickness of ∼6-8 nm. Raman analysis and AFM results confirmed the few-layered 2H phase of WS₂ nanosheets. The UV-vis study shows absorption peaks at 219 and 271 nm with large band gap value of ∼3.12 eV for WS₂ nanosheets. Surprisingly, WS₂ nanosheets show a dielectric constant of approximately ε' ≈ 5245, whereas bulk WS₂ material exhibits a dielectric constant of 7482373. An almost 1426-fold decrease in the value of dielectric constant for the WS₂ nanosheet is observed. Such an extreme reduction in dielectric constant and observance of large band gap in WS₂ nanosheet were observed for the first time. The present study reveals the excellent and unusual optical and dielectric properties for their potential application in optoelectronic, dielectric, solar, phosphor, and various nanoelectronic devices.