Inactivation of algae by visible-light-driven modified photocatalysts: A review

Harmful algal blooms have raised great concerns due to their adverse effects on aquatic ecosystems and human health. Recently, visible light-driven (VLD) photocatalysis has attracted attention for algae inactivation owing to its unique characteristics of low cost, mechanical stability, and excellent removal efficiency. However, the low utilization of visible light and the high complexation rate of electron-hole (e^--h⁺) pairs are essential drawbacks of conventional photocatalysts. Scientific efforts have been devoted to modifying VLD photocatalysts to enhance their antialgal activity. This review concisely summarizes the anti-algae performance of the latest modified VLD photocatalysts. The summary of the mechanisms in VLD photocatalytic inactivation demonstrates that reactive oxygen species (ROS) can induce oxidative damage to algal cells and photocatalytic degradation of released organic matter. In addition, the factors, such as photocatalyst dosage, algal concentration and species, and the physicochemical properties of different water matrices, such as pH, natural organic matter, and inorganic ions, affecting the efficacy of VLD catalytic oxidation for algae removal are briefly outlined. Thereafter, this review compiles perspectives on the emerging field of VLD photocatalytic inactivation.