Designed Growth of AgNP Arrays for Anti-counterfeiting Based on Surface-Enhanced Raman Spectroscopy Signals

Based on etched PS sphere arrays, the different growths of Ag nanoparticles with tunable LSPR are designed when SiO₂-25 nm/Ag-30 nm/SiO₂-100 nm sandwich nanocavity structures are annealed at 500 °C, including the hexagonal silver nanoparticle rings, circular silver nanoparticle rings, and aggregated silver nanoparticles. The uniformity of particle size and regularity of position generate enhanced electromagnetic field and good surface-enhanced Raman spectroscopy signals as confirmed by UV-vis observation and finite difference time domain method simulation. The developed nanostructures are effectively used as stable, nonreproducible, and markable anti-counterfeiting signs.