Chromic hydroxide-decorated palladium nanoparticles confined by amine-functionalized mesoporous silica for rapid
Yiyue Ding1, Wenfang Peng1, Lei Zhang1
1National Engineering Research Center for Carbohydrate Synthesis, Key Lab of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Key Laboratory of Energy Catalysis and Conversion of Nanchang, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China.
Abstract:
Formic acid (FA), one of the products of biomass conversion and CO2 reduction, has attracted much attention as a renewable liquid hydrogen carrier with a high hydrogen content (4.4 wt%). Searching for efficient catalysts to realize hydrogen evolution from FA are highly desired but challenging. Herein, ultrafine and mono-dispersed Pd-Cr(OH)3 nanoparticles (1.3 nm) loaded on amine-functionalized mesoporous silica (AFMS) have been prepared and applied as an effective catalyst for rapid hydrogen production from additive-free FA. The as-synthesized Pd-Cr(OH)3/AFMS catalysts exhibited efficient catalytic activity and 100% hydrogen selectivity and conversion toward FA dehydrogenation reaction without additives, giving an initial TOF value of 3112 h-1 at 323 K, which is comparable to most of the highly efficient heterogeneous catalysts reported so far under similar reaction conditions. This work provides a feasible idea for the design metal hydroxide-modified Pd-based efficient heterogeneous catalyst, which is expected to enhance the application of FA in fuel cells.
