A fluorescent covalent organic framework for visual detection of p-benzoquinone

P-benzoquinone (PBQ) is toxic and harmful for health. The development of portable sensor to realize the detection of PBQ is of great significance. Herein, a novel covalent organic framework (COF_ML-TFPB) with intramolecular charge transfer and aggregation induced emission properties was proposed via condensation reaction of melem (ML) and 1,3,5-tris (4-formylphenyl) benzene (TFPB). COF_ML-TFPB shows strong fluorescence in both solution and solid state and can be used for the fluorescence detection of PBQ. Due to the internal filtration effect and photoinduced electron transfer effect, PBQ can quench the fluorescence of COF_ML-TFPB. The developed COF_ML-TFPB fluorescent sensor displayed a wide linear range for PBQ from 0.138 ng mL^-1 - 35 μg mL^-1, and the detection limit was 0.046 ng mL^-1. In addition, fluorescent test paper for rapid and portable detection of PBQ was also developed by depositing COF_ML-TFPB on filter paper directly. It reduces the cost and time of detection and realizes the semiquantitative detection of PBQ. Moreover, the fluorescence color was converted into digital RGB value to calculate the concentration of PBQ accurately by a smartphone. This method realizes the portable qualitative and semiquantitative determination of PBQ.