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Published on: June 21, 2017
A low-cost commercial Cu(II)-EDTA complex for electrocatalytic water oxidation in neutral aqueous solution
Kaishan Yu1, Yue Sun1, Dingwei Zhu1
1Jiangsu Laboratory of Advanced Functional Materials, School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China. shenjunyu2014@126.com.
Abstract:
Herein, we choose a commercial Cu complex [Cu(EDTA)(H2O)] (EDTA = ethylene diamine tetraacetic acid) as a molecular catalyst for water oxidation to avoid complex synthesis and lower catalyst cost. [Cu(EDTA)(H2O)] could catalyze the water oxidation reaction efficiently under neutral conditions with an overpotential of 684 mV, a kcat of 8.03 s-1 and good stability in the long-term electrolysis. Our finding is of great significance for the development of stable, rapid, and easily accessible catalysts for water oxidation.
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