![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
Pd single-atom-site stabilized by supported phosphomolybdic acid: design, characterizations and tandem Suzuki-Miyaura
1Polyoxometalates and Catalysis Laboratory, Department of Chemistry, Faculty of Science. The Maharaja Sayajirao University of Baroda Vadodara Gujarat India anjali.patel-chem@msubaroda.ac.in.
Abstract:
Herein, a single-metal (Pd) site with high surface energy was stabilized and dispersed on a support (zirconia) via a stabilizing agent (phosphomolybdic acid) using a wet chemistry method. HRTEM and HAADF-STEM showed a highly uniform dispersion of Pd SASc on PMA/ZrO2. The Pd SASc showed superior catalytic activity (>99% conversion) for the Suzuki-Miyaura cross-coupling reaction, which was further feasible for catalyzing mechanistically different nitro hydrogenation reactions in tandem fusion under mild reaction conditions. This catalyst showed outstanding activity (100% conversion and 99% selectivity) with a substrate/catalyst ratio of 927 and TON of 918 using a very low amount of Pd (0.94 × 10-3 mmol) for the tandem Suzuki-Miyaura cross-coupling/nitro hydrogenation reaction. It also exhibited superior stability and reusability for up to three cycles without any change in its activity.
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